if you have eyeliner, lipliner or such it will only color the adj. zones (ie LIPS or Eyes) and not draw anywhere else, so not too much RL skill needed.
you just need 1 makeup of any kind to try it.
action library - start makeup session, drag the makeup on your face and start drawing.
to make little corrections is good to have 1 makeup-remover with you as well (it is more accurate than face paint etc).
to save (& wear) whatever you have created you need a makeup-mask.